MATERIAL SAFETY DATA SHEET
MSDS Number: 400476ET - 0
24 Hour Emergency Assistance: CHEMTEL (877) 276-7283
General Assistance Number: (877) 276-7285
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SECTION 1 PRODUCT IDENTIFICATION
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MATERIAL IDENTITY: Texaco Synthetic Fuel System Cleaner
PRODUCT CODES: 17316
COMPANY ADDRESS: Equilon Enterprises, LLC, P. O. Box 4453, Houston, TX.
77210-4453
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SECTION 2 PRODUCT/INGREDIENTS
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CAS# CONCENTRATION INGREDIENTS
Mixture 100 %volume Fuel System Cleaner
8008-20-6 70 - 79.99 %volume Kerosene, petroleum
Proprietary 15 - 29.99 %volume Alkylpolyalkoxidealkoxated amine
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SECTION 3 HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW
Appearance & Odor: Clear white liquid. Kerosene odor
Health Hazards: May cause skin irritation.
NFPA Rating (Health, Fire, Reactivity): 2, 2, 0
Hazard Rating: Least - 0 Slight - 1 Moderate - 2 High - 3
Extreme - 4
Inhalation:
Iin applications where vapors (caused by high temperature) or mists (caused by
mixing) are created, breathing may cause a mild burning sensation in the nose,
throat and lungs.
Eye Irritation:
Barely perceptible irritation of the eyes. If irritation occurs, a temporary
burning sensation, minor redness, swelling, and/or blurred vision may result.
Skin Contact:
May be irritating to the skin causing a burning sensation, redness and/or
swelling. Essentially non-toxic if absorbed through the skin.
Ingestion:
Generally considered to have a low order of acute oral toxicity.
Other Health Effects:
Carcinogenic in animal tests. It is probable that the material causes cancer
in laboratory animals.
This material and/or components may cause the following effects:
Genotoxicity
Primary Target Organs:
The following organs and/or organ systems may be damaged by overexposure to
this material and/or its components.
Kidney, Liver, Skin
Signs and Symptoms:
Kidney damage may be indicated by changes in urine output or appearance, pain
upon urination or in the lower back or general edema (swelling from fluid
retention). Liver damage may be indicated by loss of appetite, jaundice
(yellowish skin and eye color), fatigue and sometimes pain and swelling in the
upper right abdomen.
For additional health information, refer to section 11.
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SECTION 4 FIRST AID MEASURES
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Inhalation:
Move victim to fresh air and provide oxygen if breathing is difficult. Get
medical attention.
Skin:
Remove contaminated clothing. Flush with large amounts of water for at least
15 minutes and follow by washing with soap if available. If redness,
swelling, pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.
Eye:
Flush eyes with plenty of water while holding eyelids open. Rest eyes for 30
minutes. If redness, burning, blurred vision or swelling occur, transport to
nearest medical facility for additional treatment.
Ingestion:
DO NOT induce vomiting. DO NOT take internally. In general no treatment is
necessary unless large quantities are swallowed, however, get medical advice.
Have victim rinse mouth out with water, then drink sips of water to remove
taste from mouth. If vomiting occurs spontaneously, keep head below hips to
prevent aspiration.
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SECTION 5 FIRE FIGHTING MEASURES
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Flash Point [Method]: 129.92 ºF/54.4 ºC [ Pensky-Martens Closed Cup]
Extinguishing Media:
Material will float and can be re-ignited on surface of water. Use water fog,
'alcohol foam', dry chemical or carbon dioxide (CO2) to extinguish flames. Do
not use a direct stream of water.
Fire Fighting Instructions:
CAUTION! COMBUSTIBLE. Clear fire area of all non-emergency personnel. Do
not enter confined fire space without full bunker gear (helmet with face
shield, bunker coats, gloves and rubber boots), including a positive pressure,
NIOSH approved, self-contained breathing apparatus. Cool surrounding
equipment, fire-exposed containers and structures with water. Container areas
exposed to direct flame contact should be cooled with large quantities of
water (500 gallons water per minute flame impingement exposure) to prevent
weakening of container structure.
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SECTION 6 ACCIDENTAL RELEASE MEASURES
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Protective Measures:
CAUTION! COMBUSTIBLE. Eliminate potential sources of ignition. Handling
equipment must be bonded and grounded to prevent sparking.
Wear appropriate personal protective equipment when cleaning up spills. Refer
to Section 8.
Spill Management:
Shut off source of leak if safe to do so. Dike and contain spill.
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or
other suitable material. Place in non-leaking container and seal tightly for
proper disposal.
Reporting:
U.S. regulations require reporting releases of this material to the
environment which exceed the reportable quantity to the National Response
Center at (800)424-8802.
CWA: This product is an oil as defined under Section 311 of EPA's Clean Water
Act (CWA). Spills into or leading to surface waters that cause a sheen must be
reported to the National Response Center, 1-800-424-8802.
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SECTION 7 HANDLING AND STORAGE
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Precautionary Measures:
CAUTION! COMBUSTIBLE. Avoid heat, open flames, including pilot lights, and
strong oxidizing agents. Use explosion-proof ventilation to prevent vapor
accumulation. Ground all handling equipment to prevent sparking. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling.
Handling:
Surfaces that are sufficiently hot may ignite liquid material.
Storage:
Keep liquid and vapor away from heat, sparks and flame. Extinguish pilot
lights, cigarettes and turn off other sources of ignition prior to use and
until all vapors have dissipated. Use explosion-proof ventilation to prevent
vapor accumulation while in use.
Container Warnings:
Keep containers closed when not in use. Containers, even those that have been
emptied, can contain explosive vapors. Do not cut, drill, grind, weld or
perform similar operations on or near containers.
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SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
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Kerosene OSHA PEL TWA: 100 ppmv
Kerosene OSHA TLV TWA: 100 ppmv
EXPOSURE CONTROLS
Adequate ventilation to control airborne concentrations below the exposure
guidelines/limits. Eye washes and showers for emergency use.
PERSONAL PROTECTION
Personal protective equipment (PPE) selections vary based on potential
exposure conditions such as handling practices, concentration and ventilation.
Information on the selection of eye, skin and respiratory protection for use
with this material is provided below.
Eye Protection:
Chemical Goggles and Face Shield
Skin Protection:
Use protective clothing which is chemically resistant to this material.
Selection of protective clothing depends on potential exposure conditions and
may include gloves, boots, suits and other items. The selection(s) should
take into account such factors as job task, type of exposure and durability
requirements.
Published literature, test data and/or glove and clothing manufacturers
indicate the best protection is provided by:
Neoprene, or Nitrile Rubber
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level
which is adequate to protect worker health, an approved respirator must be
worn. Respirator selection, use and maintenance should be in accordance with
the requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134.
Types of respirator(s) to be considered in the selection process include:
For Mist: Air Purifying, R or P style NIOSH approved respirator. For Vapors:
Air Purifying, R or P style prefilter & organic cartridge, NIOSH approved
respirator. Self-contained breathing apparatus.
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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
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Appearance & Odor: Clear white liquid. Kerosene odor
Substance Chemical Family: Petroleum Hydrocarbon
Appearance: Clear colorless to light straw liquid
Boiling Point: 160 ºC - - 190 ºC Estimated
Flash Point: 54.4 ºC [Pensky-Martens Closed Cup]
Melting Point: < 22 ºF
Solubility (in Water): Negligible
Specific Gravity: 0.86 Typical
Vapor Density: > 1
Vapor Pressure: < 5 mmHg [Calculated]
Viscosity: 5 cSt
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SECTION 10 REACTIVITY AND STABILITY
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Conditions to Avoid:
Avoid heat and open flames.
Materials to Avoid:
Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products:
Thermal decomposition products are highly dependent on combustion conditions.
A complex mixture of airborne solids, liquids and gases will evolve when this
material undergoes pyrolysis or combustion. Carbon Monoxide, Unidentified
organic compounds
and other unidentified organic compounds may be formed upon combustion.
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SECTION 11 TOXICOLOGICAL INFORMATION
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Carcinogenicity Classification
Fuel System Cleaner
NTP: No IARC: No ACGIH: No OSHA: No
Carcinogenicity
Long-term skin painting of kerosene and related materials causes malignant
skin tumors in mice with long latency periods. Mechanistic studies suggest
that these tumors are a secondary effect related to prolonged skin injury and
irritation.
Genotoxicity
A kerosene-like material was found to be mutagenic in the L5178Y mouse
lymphoma assay with activation and to cause chromose damage in the in vivo rat
cytogenetics assay. The majority of genotoxicity tests conducted on kerosene
and related petroeum streams have not indicated genotoxicity or mutagenicity.
Kidney
***** -Reference ID#10488- *****Nephropathy appears to be male rat specific
(accumulation of alpha-2-u globulin) and is probably not relevant to humans.
Liver
***** -Reference ID#10488- *****Tissue damage observed in the liver (mottled
necrosis and centrilobular degeneration) kidney and bladder (hyperplasia) was
considered to be secondary to the severe skin irritancy.
Skin
Repeated high level dermal exposure of the skin results in severe irritation
and histopathologic changes including inflammatory cell infiltration,
acanthosis, fibrosis, hyperkeratosis and scab formation. All changes appear to
be related to chronic irritation.
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SECTION 12 ECOLOGICAL INFORMATION
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Environmental Impact Summary:
There is no ecological data available for this product.
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SECTION 13 DISPOSAL CONSIDERATIONS
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RCRA Information:
If this material, as it is originally purchased, were subsequently DISCARDED
as a waste, the waste would be a RCRA hazardous waste.
D001 (Ignitable Hazardous Waste)
Under RCRA, it is the responsibility of the user of the material to determine,
at the time of the disposal, whether the material meets RCRA criteria for
hazardous waste. This is because material uses, transformations, mixtures,
processes, etc. may affect the classification. Refer to the latest EPA, state
and local regulations regarding proper disposal.
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SECTION 14 TRANSPORT INFORMATION
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US Department of Transportation Classification
Hazard Class/Division: Combustible Liquid
Packing Group: III
Marine Pollutant % of Total: 12 %weight
Marine Pollutant: For DOT exceptions that apply to this
material, see 49 CFR 172.203(L)(3) and 171.4(c).
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail
or highway in a tank with a capacity of 3500 gallons or more, it is subject to
these requirements. Mixtures or solutions containing 10% or more of this
product may also be subject to this rule.
Emergency Response Guide # Liquid: 128
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SECTION 15 REGULATORY INFORMATION
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FEDERAL REGULATORY STATUS
OSHA Classification:
Product is hazardous according to the OSHA Hazard Communication Standard, 29
CFR 19.10.1200.
Comprehensive Environmental Release, Compensation & Liability Act (CERCLA):
Clean Air Act (CAA):
This material is classified as a Hazardous Air Pollutant under the Clean Air
Act (CAA).
Ozone Depleting Substances (40 CFR 82 Clean Air Act):
This material does not contain nor was it directly manufactured with any Class
I or Class II ozone depleting substances.
Superfund Amendment & Reauthorization Act (SARA) Title III:
There are no components in this product on the SARA 302 list.
SARA Hazard Categories (311/312):
Immediate Health:YES Delayed Health:YES Fire:YES Pressure:NO
Reactivity:NO
SARA Toxic Release Inventory (TRI) (313):
There are no components in this product on the SARA 313 list.
Toxic Substances Control Act (TSCA) Status:
This material is listed on the EPA/TSCA Inventory of Chemical Substances.
Other Chemical Inventories:
Australian AICS, Canadian DSL, Chinese Inventory, European EINECS, Japan
ENCS, Korean Inventory, Philippines PICCS
State Regulation
The following chemicals are specifically listed by individual states; other
product specific health and safety data in other sections of the MSDS may also
be applicable for state requirements. For details on your regulatory
requirements you should contact the appropriate agency in your state.
New Jersey Right-To-Know Chemical List:
Aminoethyanolamine (0074) 15 - 29.99 %volume Special Hazard
Pennsylvania Right-To-Know Chemical List:
Aminoethyanolamine (111-41-1) 15 - 29.99 %volume Environmental Hazard
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SECTION 16 OTHER INFORMATION
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HMIS Rating (Health, Fire, Reactivity): 1, 2, 0
Revision#: 0
Revision Date: 08/02/2000
Revisions since last change (discussion): This Material Safety Data Sheet has
changed because Equiva Services LLC. has implemented new software to generate
the sheet. There will be slight differences in the hazard and precautionary
language as we incorporate the guidance contained in the ANSI MSDS standard
(ANSI Z400.1-1998). There are no significant changes to the health, safety or
precautionary messages. We encourage you to take the opportunity to reread
the sheet and review the information contained.
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SECTION 17 LABEL INFORMATION
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READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF
PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL
IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND
MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR
OTHER RELATED REGULATORY REQUIREMENTS.
PRODUCT CODES: 17316
Texaco Synthetic Fuel System Cleaner
CAUTION!
COMBUSTIBLE LIQUID! MAY CAUSE SKIN IRRITATION. PROLONGED OR REPEATED SKIN
CONTACT MAY CAUSE OIL ACNE OR DERMATITIS.
Precautionary Measures:
Avoid contact with skin and clothing. Avoid heat and open flames. Use only
with adequate ventilation. Avoid contact with eyes, skin and clothing. Keep
container closed when not in use. Wash thoroughly after handling.
FIRST AID
Inhalation: Move victim to fresh air and provide oxygen if breathing is
difficult. Get medical attention.
Skin Contact: Remove contaminated clothing. Flush with large amounts of
water for at least 15 minutes and follow by washing with soap if available.
If redness, swelling, pain and/or blisters occur, transport to the nearest
medical facility for additional treatment.
Eye Contact: Flush eyes with plenty of water while holding eyelids open.
Rest eyes for 30 minutes. If redness, burning, blurred vision or swelling
occur, transport to nearest medical facility for additional treatment.
Ingestion: DO NOT induce vomiting. If vomiting occurs spontaneously, keep
head below hips to prevent aspiration. Have victim rinse mouth out with
water, then drink sips of water to remove taste from mouth. In general no
treatment is necessary unless large quantities are swallowed, however, get
medical advice.
FIRE
In case of fire, Use water fog, 'alcohol foam', dry chemical or carbon
dioxide (CO2) to extinguish flames. Do not use a direct stream of water.
Material will float and can be re-ignited on surface of water.
SPILL OR LEAK
Dike and contain spill.
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or
other suitable material. Place in non-leaking container and seal tightly for
proper disposal.
CONTAINS: Kerosene, petroleum, 8008-20-6; Alkylpolyalkoxidealkoxated amine,
Proprietary
NFPA Rating (Health, Fire, Reactivity): 2, 2, 0
HMIS Rating (Health, Fire, Reactivity): 1, 2, 0
TRANSPORTATION
US Department of Transportation Classification
Hazard Class/Division: Combustible Liquid
Packing Group: III
Marine Pollutant % of Total: 12 %weight
Marine Pollutant: For DOT exceptions that apply to this
material, see 49 CFR 172.203(L)(3) and 171.4(c).
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail
or highway in a tank with a capacity of 3500 gallons or more, it is subject to
these requirements. Mixtures or solutions containing 10% or more of this
product may also be subject to this rule.
Emergency Response Guide # Liquid: 128
Name and Address
Equilon Enterprises, LLC
P. O. Box 4453
Houston, TX 77210-4453
TRANSPORTATION EMERGENCY CHEMTEL (877) 276-7283
HEALTH EMERGENCY CHEMTEL (877) 276-7283
ADMINISTRATIVE INFORMATION
COMPANY ADDRESS: Equilon Enterprises, LLC, P. O. Box 4453, Houston, TX.
77210-4453
Company Product Stewardship & Regulatory Compliance Contact: Timothy W Childs
MSDS FAX-BACK Phone Number: (877) 276-7285
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO
US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN.
YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR
DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH
SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT
TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE
GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE
RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE
UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA,
IS THE PROPERTY OF EQUIVA SERVICES, LLC AND IS NOT TO BE THE SUBJECT OF SALE
OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF EQUIVA SERVICES, LLC.
33843-11617-100R-2000-08-02 15:44:43